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     EduGorilla 
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    Decomposition of A in a rigid closed vessel takes place as A(g) 3B(g), which follows 1st order kinetics. Reaction is started with an equimolar mixture of a gas A and an inert gas X. The initial pressure was 4 atm and at the end of 20 min, the total pressure is 6 atm. The time required for 75% reaction of A will be

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